Malachite

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Malachite

Malachite from the Congo
General
Category Carbonate mineral
Chemical formula Cu2CO3(OH)2
Strunz classification 05.BA.10
Identification
Molar mass 221.1 g/mol
Color Bright green, dark green, blackish green, commonly banded in masses; green to yellowish green in transmitted light
Crystal habit Massive, botryoidal, stalactitic, crystals are acicular to tabular prismatic
Crystal system Monoclinic—prismatic H-M Symbol (2/m) Space group P21/a
Twinning Common as contact or penetration twins on {100} and {201}. Polysynthetic twinning also present.
Cleavage Perfect on {201} fair on {010}
Fracture Subconchoidal to uneven
Mohs scale hardness 3.5–4.0
Luster Adamantine to vitreous; silky if fibrous; dull to earthy if massive
Streak light green
Diaphaneity Translucent to opaque
Specific gravity 3.6–4
Optical properties Biaxial (–)
Refractive index nα = 1.655 nβ = 1.875 nγ = 1.909
Birefringence δ = 0.254
References <ref name=Handbook>Malachite in Handbook of Mineralogy</ref><ref>Malachite at Webmineral</ref><ref name=Mindat>Malachite at Mindat</ref>

Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This green-colored mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and spaces, deep underground, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare but do occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur<ref name=Mindat/>. Typical malachite is laminated and whether or not microbes intervene in its formation is unknown.

Etymology and history

The stone's name derives (via Latin: molochītis, Middle French: melochite, and Middle English melochites) from Greek Μολοχίτης λίθος molochitis lithos, "mallow-green stone", from μολόχη molōchē, variant of μαλάχη malāchē, "mallow".<ref>Malachite, Dictionary.com</ref> The mineral was given this name due to its resemblance to the leaves of the Mallow plant.<ref>Harper, Douglas. "malachite". Online Etymology Dictionary. http://www.etymonline.com/index.php?term=malachite. </ref>

Malachite was used as a mineral pigment in green paints from antiquity until about 1800. The pigment is moderately lightfast, very sensitive to acids and varying in color. The natural form was being replaced by its synthetic form, verditer amongst other synthetic greens. It is also used for decorative purposes, such as in the Malachite Room in the Hermitage, which features "The Tazza", a large malachite vase and one of the largest pieces of malachite in North America. A gift from Tsar Nicholas II, it stands as the focal point in the center of the room of Linda Hall Library.

Archeological evidence indicates that the mineral has been mined and smelted at Timna valley in Israel for over 3,000 years.<ref>Parr, Peter J review of "Timma: Valley of the Biblical Copper Mines" by Beno Rothenberg Bulletin of the School of Oriental and African Studies, University of London, Vol. 37, No. 1, In Memory of W. H. Whiteley (1974), pp. 223–224</ref>

Occurrence

Malachite often results from weathering of copper ores and is often found together with azurite (Cu3(CO3)2(OH)2), goethite, and calcite. Except for its vibrant green color, the properties of malachite are similar to those of azurite and aggregates of the two minerals occur frequently. Malachite is more common than azurite and is typically associated with copper deposits around limestones, the source of the carbonate.

Large quantities of malachite have been mined in the Urals, Russia. It is found worldwide including in the Democratic Republic of Congo; Gabon; Zambia; Tsumeb, Namibia; Mexico; Broken Hill, New South Wales; Lyon, France; Timna valley, Israel, and in the Southwestern United States notably in Arizona.<ref>Mindat map with over 8500 locations</ref>

Malachite gallery

See also

References

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Further reading

ar:مالاكايت

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